Borate links

<ref name=chen2013>Fuzhen Chen, Hanqiao Jiang, Xiaohu Bai, Wei Zheng (2013): "Evaluation the performance of sodium metaborate as a novel alkali in alkali/surfactant/polymer flooding". ''Journal of Industrial and Engineering Chemistry'' volume 19, pages 450–457. {{doi|10.1016/j.jiec.2012.08.029}}</ref>
<ref name=1955>John O. Edwards, Glenn C. Morrison, Virginia F. Ross, and John W. Schultz (1955): "The Structure of the Aqueous Borate Ion". ''Journal of the American Chemical Association'', volume 77, issue 2, pages 266–268. {{doi|10.1021/ja01607a005}}</ref>
Scholar: [metaborate ion].
Scholar: [pyroboric acid CAS]
Scholar: [Na2B4O5(OH)4]
Scholar: [tetrahydroxyborate]
Scholar: [Na2B8O13]
Scholar: [Crystallisation of sodium octaborate]
Scholar: []

<ref name=yasu1965>Tatsuya Yasunaga, Nobuhide Tatsumoto, and Masaji Miura (1965): "Ultrasonic Absorption in Sodium Metaborate Solution". ''Journal of Chemical Physics'' volume 43, pages 2735-. {{doi|10.1063/1.1697202}}</ref>
<ref name=fang1938>Ssu-Mien Fang (1938): "The Crystal Structure of Sodium Metaborate Na3 (B3 O6)". ''Zeitschrift für Kristallographie - Crystalline Materials'', volume 99, issue 1-6, pages 1-8. {{doi|10.1524/zkri.1938.99.1.1}}</ref>
<ref name=zhou2017>Yongquan Zhou, Souta Higa, Chunhui Fang, Yan Fang, Wenqian Zhang, and Toshio Yamaguchi (2017): "B(OH)4− hydration and association in sodium metaborate solutions by X-ray diffraction and empirical potential structure refinement". ''Physical Chemistry Chemical Physics'', volume 19, pages 27878-27887. {{doi|10.1039/C7CP05107G}}</ref>
<ref name=petr1999>G. A. Petrakovskii, K. A. Sablina, D. A. Velikanov, A. M. Vorotynov, N. V. Volkov, and A. F. Bovina (1999): "Weak ferromagnetism in copper metaborate CuB2O4". ''Physics of the Solid State'', volume 41, pages 1157–1161. {{doi|10.1134/1.1130957}}</ref>
<ref name=mare1963d>M. Marezio, H. A. Plettinger and W. H. Zachariasen (1963): "The crystal structure of potassium tetraborate tetrahydrate". ''Acta Crystallographica'', volume 16, pages 975-980. {{doi|10.1107/S0365110X63002619}}</ref>
<ref name=rous1992>Y. Roussigné, R. Farhi, C. Dugautier, and J. Godard (1992): "A Raman study of both phases of barium metaborate (BBO)". ''Solid State Communications''. volume 82, issue 4, pages 287-293. {{doi|10.1016/0038-1098(92)90643-N}}
<ref name=zhou2017>Yongquan Zhou, Souta Higa, Chunhui Fang, Yan Fang, Wenqian Zhang, and Toshio Yamaguchi (2017): "B(OH)4− hydration and association in sodium metaborate solutions by X-ray diffraction and empirical potential structure refinement". ''Physical Chemistry Chemical Physics'', volume 19, pages 27878-27887 {{doi|10.1039/C7CP05107G}}
<ref name=uysa2017>Duygu Uysal, Özkan Murat Dogan, Bekir Zühtü Uysal (2017): "Kinetics of Absorption of Carbon Dioxide into Sodium Metaborate Solution". ''International Journal of Chemical Kinetics'', volume 49, issue 6, pages 377-386. {{doi|10.1002/kin.21082}}
<ref name=clou2007>Caroline R. Cloutier, Akram Alfantazi, Elod Gyenge (2007): "Physicochemical Properties of Alkaline Aqueous Sodium Metaborate Solutions". ''Journal of Electrochemical Energy Conversion and Storage'' (formerly ''Journal of Fuel Cell Science and Technology''), volume 4, issue 1, pages 88-98. {{doi|10.1115/1.2393310}}
<ref name=zach1931>W. H. Zachariasen (1931): "The Crystal Lattice of Calcium Metaborate, CaB2O4". ''Proceedings of the National Academy of Sciences (PNAS)'', volume 17, issue 11, pages 617-619. {{doi|10.1073/pnas.17.11.617}}
<ref name=feat1973>David H. Feather and Alfred Buechler (1973): "Gaseous thallium(I) metaborate and thallium(I) aluminum fluoride". ''Journal of Physical Chemistry'', volume 77, issue 12, pages 1599–1600. {{doi|10.1021/j100631a027}}
<ref name=petr1999> G. Petrakovskii, D Velikanov, A. Vorotinov, A Balaev, K Sablina, A. Amato, B. Roessli, J. Schefer, U Staub (1999): "Weak ferromagnetism in CuB2O4 copper metaborate". ''Journal of Magnetism and Magnetic Materials'', volume 205, issue 1, pages 105-109. {{doi|10.1016/S0304-8853(99)00449-7}}
<ref name=zhou2012>Yongquan Zhou, Chunhui Fang, Yan Fang, Fayan Zhu, Song Tao, Sha Xu (2012): "Structure of aqueous sodium metaborate solutions: X-ray diffraction study". ''Russian Journal of Physical Chemistry, volume 86, issue 8, pages 1236–1244. {{doi|10.1134/S0036024412060349}}
<ref name=fige2010>Aysel Kantürk Figen, Sabriye Pişkin (2010): "Parametric investigation on anhydrous sodium metaborate (NaBO2) synthesis from concentrated tincal". ''Advanced Powder Technology'', volume 21, issue 5, september , pages 513-520. {{doi|10.1016/j.apt.2010.01.012}} [NaBO2 compounds, 4-hydrate, 2-hydrate and dehydrate, are classified by the amount of water they contain. The molecular structure of 4-hydrated sodium metaborate has been described as NaB(OH)4.2H2O according to the X-ray diffraction (XRD) analysis [16]. In addition to this, thermal analysis of NaB(OH)4.2H2O compound is performed to identify the characteristics of transition behavior to other forms. It is shown that NaB(OH)4.2H2O losses the crystalline and structure water at around 310 °C and these overall dehydration steps can be expressed as follows [17]:(3) NaB(OH)4.2H2O -> NaB(OH)4 -> NaBO2 It is presented that hydrate NaBO2 compound is synthesized by hydrothermal method from a mixture of borax (Na2B4O7) with sodium hydroxide (NaOH) according to Eq. (5) [17].(5) The standard NaBO2.4H2O, was dried at 370 °C for 5 h in the calibrated oven to obtain standard anhydrous NaBO2. At 200 C the product was sodium boron hydroxide Na3B3O5(OH)2 and Sodium borate hydroxide hydrate Na2B2(O2)2(OH)4(H2O)6. At 300 C Sodium borate hydrate NaBO2.2H2O, Sodium borate NaBO2, Sodium borate hydrate Na2(BO2(OH)), Sodium borate hydrate NaBO3.2H2O. ]
<ref name=caka2008>Çetin Çakanyıldırım, MetinGürü (2008): "Hydrogen cycle with sodium borohydride". ''International Journal of Hydrogen Energy'', volume 33, issue 17, september , pages 4634-4639. {{doi|10.1016/j.ijhydene.2008.05.084}} [Synthesis if trimethoxyboron frm sodium borates using CaCl2 as dehydratant. It is well known that 50–60 g of CaCl2 is adequate to dehydrate approximately 255 g of reactant.]
<ref name=mare1963>M. Marezio, H. A. Plettinger and W. H. Zachariasen (1963): "The bond lengths in the sodium metaborate structure". ''Acta Crystallographica'', volume 16, pages 594-595. {{doi|10.1107/S0365110X63001596}}
<ref name=mare1963b>M. Marezio, H. A. Plettinger and W. H. Zachariasen (1963): "Refinement of the calcium metaborate structure". ''Acta Crystallographica'', volume 16, pages 390-392. {{doi|10.1107/S0365110X63001031}}
<ref name=mare1963c>M. Massimo Marezio, H. A. Plettinger and W. H. Zachariasen (1963): "The crystal structure of potassium tetraborate tetrahydrate". ''Acta Crystallographica'', volume 16, pages 975-980. {{doi|10.1107/S0365110X63002619}} [K2B4O7.4H2O = K2[B4O5(OH)4].2H2O. The structure contains the complex ion [B4O5(OH)4] 2- consisting of two boron-oxygen triangles and two tetrahedra which have only corners in common.Single crystals were prepared by slow evaporation from aqueous solutions. Same anion as borax. ]
<ref name=mare1966>M. Marezio and J. P. Remeika (1966): "Polymorphism of LiMO2 Compounds and High‐Pressure Single‐Crystal Synthesis of LiBO2". ''Journal of Chemical Physics'', volume 44, issue 9, pages 3348-. {{doi|10.1063/1.1727236}} [gamma form of LiBO2, stabe at high pressures and temperatures. 15 kbar and at 950°C. Infinite lattice of B-O tetrahedra alternating with LiO tetrahedra. B-O distance 148.3 pm, Li-O 196 pm. ]
<ref name=wacla1995>I. Waclawska (1995): "Thermal decomposition of borax". ''Journal of Thermal Analysis'', volume 43, pages 261–269 . {{doi|10.1007/bf02635993}}</ref>
<ref name=senn2007>N. A. Sennova, R. S. Bubnova, S. K. Filatov, and I. G. Polyakova (2007): "High-temperature crystal chemistry of α-Na2B4O7 and β-NaB3O5 layered borates". ''Glass Physics and Chemistry'', volume 33, pages 217–225 . {{doi|10.1134/S1087659607030054}}</ref>
<ref name=burg1905>Charles Hutchens Burgess, Alfred Holt, Junior (1905): "Some Physical Characters of the Sodium Borates, with a New and Rapid Method for the Determination of Melting Points". ''Proceedings of the Royal Society of London'' volume 74, pages 497-506. {{doi|10.1098/rspl.1904.0112}}</ref>
<ref name=cala2006>Calabretta, D.L. (2006): "[https://www.elibrary.ru/item.asp?id=9417987 Investigations on the Hydride Rich Region of the Sodium-Boron-Oxygen-Hydrogen System]". MS Thesis, Queen's University at Kingston, Canada.</ref>
<ref name=ghan1993>Kazem Ghanbari-Ahari, Andrew M. Cameron (1993): "Phase Diagram of Na2O-B2O3-SiO2 System". ''Journal of the American Ceramic Society'', 76, pages 2017-2022 . {{doi|10.1111/j.1151-2916.1993.tb08326.x}}</ref>
<ref name=krog1959>Jan Krogh-Moe (1959): "[https://www.proquest.com/openview/57f7245a2f756098a933f1d2b946cbe5/1 On the Structure of Boron Oxide and Alkali Borate Glasses]". DR Thesis, Göteborg Univ.</ref>
<ref name=osip2010>A.A.Osipov, L.M.Osipova (2010): "Structural studies of Na2O–B2O3 glasses and melts using high-temperature Raman spectroscopy". ''Physica B: Condensed Matter'', volume 405, issue 23, pages 4718-4732. {{doi|10.1016/j.physb.2010.08.025}}</ref>
<ref name=brau1963>Georg Brauer (1963): [https://library.sciencemadness.org/library/books/brauer_ocr.pdf ''Handbook of Preparative Inorganic Chemistry''], edition 2, volume 1. {{isbn|978-0-12-395590-6}} {{doi|}}</ref>

<ref name=tujm1995>Tu, Jun-Ming (1995): "[https://www.proquest.com/openview/62004e8ae089bd8660f61e43ac9e7929/1 New alkali-metal and alkaline-earth metal borates: Synthesis, crystal structures, and optical properties]". DR Thesis, Oregon State University.</ref>
<ref name=1936>G. W. Morey and H. E. Merwin (1936): "Phase Equilibrium Relationships in the Binary System, Sodium Oxide-Boric Oxide, with Some Measurements of the Optical Properties of the Glasses". ''Journal of the American Chemical Association'', volume 58, issue 11, pages 2248–2254. {{doi|10.1021/ja01302a048}}</ref>
<ref name=2010>Jérôme Andrieux, Christelle Goutaudier, Laetitia Laversenne, Erwann Jeanneau, Philippe Miele (2010): "Synthesis, Characterization, and Crystal Structure of a New Trisodium Triborate, Na3[B3O4(OH)4]". ''Inorganic Chemistry'', volume 49, issue 11, pages 4830–4835. {{doi|10.1021/ic902525s}}</ref>
<ref name=CHEBI38909&gb;ChEBI: "Trisodium borate Na3BO3". CHEBI entry 38909</ref>
<ref name=thom1946>Leo H. Thomas (1946): "The preparation of simple organic orthoborates". ''Journal of the Chemical Society (Resumed)'', article 176, pages820-.</ref>
<ref name=websterBoracic>Merriam-Webster: "boracic acid".</ref>
<ref name=websterTincal>Merriam-Webster: "tincal".</ref>
<ref name=stackDiolBor>Ankit Kumar Misra (2019): "Can ethylene glycol enhance the acidity of orthoboric acid?" StackExchange Chemistry website. Acessed on 2022-07-25.</ref>
<ref name=harrXXXX>Bennett Harry (??): "[https://patents.google.com/patent/US1953741A/en Reaction products of glycols and boric acid and method of producing the same]". Patent US1953741A
</ref>
<ref name=freyXXXX>Clemens C. Freyhardt, Michael Wiebcke, Jürgen Felsche (??): "The Monoclinic and Cubic Phases of Metaboric Acid (Precise Redeterminations)". ''Acta Crystallographica Section C Crystal Structure Communications'' volume 56 (Pt 3)(25), pages 276-278. {{doi|10.1107/S0108270199016042}}</ref>
<ref name=mariXXXX>S. Maričić, V. Pravdić, Z. Veksli (??): "Proton conductivity in borax, Na2[B4O5(OH)4]-8H2O". ''''. {{doi|10.1016/0022-3697(62)90248-2}}</ref>
<ref name=PubChemXXXX>PubChem: "Tetraborate(2-)". Entry CID ??. Accessed on 2022-07-24.
<ref name=PubChem90479350>PubChem: "Disodium octaborate" Entry CID 90479350. Accessed on 2022-07-24.
<ref name=mccu1937>L. McCulloch (1937): "A Crystalline Boric Oxide". ''Journal of the American Chemical Association'', volume 59, issue 12, pages 2650–2652 . {{doi|10.1021/ja01291a05}}</ref>
<ref name=vish2015>I. Vishnevetsky and M. Epstein (2015): "Solar carbothermic reduction of alumina, magnesia and boria under vacuum". ''Solar Energy'' volume 111, pages 236-251. {{doi|10.1016/j.solener.2014.10.039}}</ref>
<ref name=NEMS1989>Linda M. Murray (1989): "Least Toxic Pest Controls: How Infestations of Termites, Anta, Fleas, Ticks, and Beetles Can Be Controlled without Causing Short- or Lon-Term Indoor Air Quality Changes and Health Risks". US EPA NEMS Program.</ref>
<ref name=sahiXXXX>Ömer Şahin and A. Nureset Bulutcu (??): "Dehydration Behaviour of Borax Pentahydrate to Anhydrous Borax by Multi-Stage Heating in a Fluidized". ''Turkish Journal of Chemistry'', volume 26, issue 1, article 10. {{doi|10.1.1.533.2260}}</ref>
<ref name=cset1993>L. J. Csetenyi, F. P. Glasser and R. A. Howie (1993): "Structure of sodium tetrahydroxyborate". ''Acta Crystallographica'', volume C49, pages 1039-1041. {{doi|10.1107/S0108270193000058}}</ref>
<ref name=dawb1986>J. Graham Dawber, Stuart I. E. Green (1986): "An 11B nuclear magnetic resonance study of the reaction of the tetrahydroxyborate ion with polyhydroxy compounds". ''Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases'', issue 11. {{doi|10.1039/F19868203407}}</ref>
<ref name=zhuf2020>Fayan Zhu, Wenqian Zhang, Hongyan Liu, Xiufang Wang, Yongquan Zhou, Chunhui Fang, Yunhong Zhang (2020): "Micro–Raman and density functional theory analyses of ion pairs in concentrated sodium tetrahydroxyborate droplets" ''Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy'', volume 224, pages 117308-. {{doi|10.1016/j.saa.2019.117308}}</ref>
<ref name=dawb1987>J. Graham Dawber (1987): "A polarimetric, circular dichroism and 11B nuclear magnetic resonance study of the reaction of the tetrahydroxyborate ion with two chiral 1,3-diols". ''Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases '', volume 83, issue 3, 771-777. {{doi|10.1039/F19878300771}}</ref>
<ref name=2004>Masanori Tachikawa (2004): "A density functional study on hydrated clusters of orthoboric acid, B(OH)3(H2O)n (n=1–5)". ''Journal of Molecular Structure: THEOCHEM'', volume 710, issues 1–3, pages 139-150. {{doi|10.1016/j.theochem.2004.09.008}}</ref>
<ref name=seli2018>Veysel Selimoglu, M. Muhtar Kocakerim (2018): "Optimization of Dissolution of Ulexite by Pure CO2 Gas in Aqueous Medium under Pressure and Production of Sodium Pentaborate". ''International Journal of Chemistry and Technology'', volume 2, issue 2, pages 123-128. {{doi|10.32571/ijct.467098}}</ref>
<ref name=senn2007>N. A. Sennova, R. S. Bubnova, S. K. Filatov, and I. G. Polyakova (2007): "High-temperature crystal chemistry of α-Na2B4O7 and β-NaB3O5 layered borates". ''Glass Physics and Chemistry'', volume 33, pages 217–225. {{doi|10.1134/S1087659607030054}}</ref>
<ref name=hellXXXX>Gert Heller (??): "A survey of structural types of borates and polyborates". ''Topics in Current Chemistry'', volume 131: ''Structural Chemistry of Boron and Silicon'', pages 39-98. {{isbn|978-3-540-15811-0}} {{doi|10.1007/3-540-15811-1_2}}</ref>
<ref name=corr1975a>E. Corazza, S. Menchetti and C. Sabelli (1975): "The crystal structure of Na3[B3O5(OH2)]". ''Acta Crystallographica B'', volume B31, pages 1993-1997. {{doi|10.1107/S056774087500670X}}</ref>
<ref name=corr1975b>E. Corazza, S. Menchetti and C. Sabelli (1975): "The crystal structure of nasinite, Na2[B5O8(OH)].2H2O". ''Acta Crystallographica B'', volume B31, pages 2405-2410 . {{doi|10.1107/S0567740875007704}}</ref>
<ref name=menc1977>S. Menchetti and C. Sabelli (1977): "The Crystal Structure of Sodium Pentaborate Monohydrate". ''Acta Crystallographica B'', volume B33, pages 3730-3733. {{doi|10.1107/S0567740877011959}}</ref>
<ref name=1978a>S. Menchetti and C. Sabelli (1978): "The crystal structure of NaB5O6(OH)4". ''Acta Crystallographica B'', volumeB34, pages 45-49. {{doi|10.1107/S0567740878002289}}</ref>
<ref name=menc1978b>S. Menchetti (1978): "The crystal structure of Na2[B4O6(OH)2]". ''Acta Crystallographica B'', volume B34, pages 1080-1084. {{doi|10.1107/S0567740878004963}}</ref>
<ref name=1979>S. Menchetti and C. Sabelli (1979): "A new borate polyanion in the structure of N8[B12O20(OH)4]". ''Acta Crystallographica B'', volume B35, pages 2488-2493. {{doi|10.1107/S0567740879009742}}</ref>
<ref name=menc1982a>S. Menchetti and C. Sabelli (1982): "The Structure of Sodium Borate Na3(B5O9)*H2O.". ''Acta Crystallographica B'', volume B38, pages 2987-2991. {{doi|10.1107/S0567740882010656}}</ref>
<ref name=menc1982b>S. Menchetti and C. Sabelli (1982): "Structure of hydrated sodium borate Na2[BO2(OH)]". ''Acta Crystallographica B'', volume B38, pages 1282-1285. {{doi|10.1107/S0567740882005512}}</ref>
<ref name=yuzt2002>Zhen-Tao Yu, Zhan Shi, Yu-Sheng Jiang, Hong-Ming Yuan, and Jie-Sheng Chen (2002): "A Chiral Lead Borate Containing Infinite and Finite Chains Built up from BO4 and BO3 Units". ''Chemistry of Materials'', volume 14, issue 3, pages 1314–1318. {{doi|10.1021/cm010387k}}</ref>
<ref name=toub2003>Marcel Touboul, Nicolas Penin, Guy Nowogrocki (2003): "Borates: a survey of main trends concerning crystal-chemistry, polymorphism and dehydration process of alkaline and pseudo-alkaline borates". ''Solid State Sciences'', volume 5, issue 10, pages 1327-1342. {{doi|10.1016/S1293-2558(03)00173-0}}</ref>
<ref name=lixh2022>Xiaohui Li, Li Yang, Zhenyu Zhu, Xiaoge Wang, Pohua Chen, Senchuan Huang, Xianyi Wei, Guohong Cai, Pascal Manuel, Sihai Yang, Jianhua Lin, Xiaojun Kuang, and Junliang Sun (2022): "Borates as a new direction in the design of oxide ion conductors". ''Science China Materials'', 9 pages. {{doi|10.1007/s40843-022-2044-3}}</ref>
<ref name=berm1994>Vladimir Bermanec, Thomas Armbruster, Darko Tibljas, Darko Sturman, and Goran Kniewald (1994): "Tuzlaite, NaCa[B5O8(OH)2]·3H2O, a new mineral with a pentaborate sheet structure from the Tuzla salt mine, Bosnia and Hercegovina". ''American Mineralogist'', volume 79, issue 5-6, pages 562–569. No DOI.</ref>
<ref name=zhang2004>H.-X. Zhang, S.-T. Zheng and G.-Y. Yang (2004): "Tetramethylammonium pentaborate 0.25-hydrate". ''Acta Crystallographica C'', volume C60, pages o545-o546. {{doi|10.1107/S0108270104013915}}</ref>
<ref name=tara1987>B. P. Tarasevich and Evgenii V Kuznetsov (1987): "Progress in the Polymer Chemistry of Borates". ''Russian Chemical Reviews'', volume 56, issue 3, pages 203-. {{doi|10.1070/RC1987v056n03ABEH003266}}</ref>
<ref name=skak>Mahmood Skakibaie-Moghadam, Gert Heller and Ulrich Timper: "Die Kristallstruktur von Ag6[B12O18(OH)6] ⋅ 3 H2O, einem neuen Dodekaborat". ''Zeitschrift für Kristallographie - Crystalline Materials'', volume 190, issue 1-4. {{doi|10.1524/zkri.1989.190.14.85}}</ref>
<ref name=menc1982c>S. Menchetti, C. Sabelli, and R. Trosti-Ferroni (1982): "La struttura cristallina di Na3[B5O9]•H2O". ''Rendiconti della Societa Italiana di Mineralogia e Petrologia'', volume 38, issue 2, page 909. No DOI.</ref>
<ref name=menc1982d>S. Menchetti,C. Sabelli, and R. Trosti-Ferroni (1982): "Raffinamento della struttura della probertite CaNa[B5O7(OH)4]•3H2O". ''Rendiconti della Societa Italiana di Mineralogia e Petrologia'', volume 38, issue 2, pages 909-910. No DOI.</ref>

<ref name=menc1982e>S. Menchetti, C. Sabelli and R. Trosti-Ferroni (1982): "Probertite, CaNa[B5O7(OH)4].3H2O: a refinement". ''Acta Crystallographica B'' volume B38, pages 3072-3075. {{doi|10.1107/S0567740882010851}}</ref>
<ref name=menc1983>S. Menchetti, C. Sabelli, A. Soppioni, and R. Trosti-Ferroni (1983): "Hydrothermal synthesis at 250°C and X-ray study of resulting products in the NaOH-B2O3-H2O system". ''Neues Jahrbuch für Mineralogie. Abhandlungen'', volume 148, issue 2, pages 163-180. No DOI. [The 250°C isothermal section of the NaOH-B2O3-H2O system was studied under hydrothermal conditions. To define the phase fields, 77 starting compositions were needed. The run products were investigated by powder XRD. The compounds have the Na2O:B2O3:H2O molar proportions with crystal chemical formulae 2:1:1, Na2(BO2(OH)); 1:1:0, Na(BO2); 2:3:1, Na8(B12O20(OH)4) (new phase); 3:5:2, Na3(B5O9).H2O (new phase); 1:2:1, Na2(B4O6(OH)2); 2:5:3, Na4(B10O16(OH)2).2H2O (biringuccite); 0:1:3, B(OH)3 (sassolite); and an as yet unidentified phase 'F'. Unit-cell data of these compounds are given.]</ref>
<ref name=bona1987>P. Bonazzi, S. Menchetti, C. Sabelli and R. Trosti-Ferroni (1987): "Two different borate groups in the structure of HNa10[B18O30(OH)5]". ''Zeitschrift für Kristallographie - Crystalline Materials'', volume 180, issue 1-4. {{doi|10.1524/zkri.1987.180.14.51}}</ref>
<ref name=>Open Quantum Materials Database: "Na3B5H2O10". '''' [DOI]
<ref name=>Menchetti, S., Sabelli, C., Trosti-ferroni, R.: "The Structure of Sodium Borate Na3(B5O9)*H2 O.". ''''. {{doi|10.1107/S0567740882010656}}</ref>
<ref name=>P. Bonazzi, S. Menchetti, C. Sabelli, R. Trosti-Ferroni: "Two different borate groups in the structure of HNa10[B18O30(OH)5]". ''''. {{doi|10.1524/zkri.1987.180.1-4.51}}</ref>
<ref name=>Y Liu: "Exploring The Synthesis Of Borates With Nonlinear Optical Properties". MS Thesis [DOI]
<ref name=>Thomas Pauly, V. Petkov, Yu Liu, S.J.L. Billinge: "Role of framework sodium versus local structure in determining the hydrothermal MCM-41 mesostructures". ''Journal of the American Chemical Society 124(1):99-105 '' [DOI]
<ref name=>Cory C. Pye: "A Crystallographic Review of Alkali Borate Salts and Ab Initio Study of Borate Ions/Molecules". ''''''''. {{doi|10.1007/978-3-319-74582-4_7}}</ref>
<ref name=>John Krc: "Crystallographic Data. 44. Sodium Metaborate Dihydrate". ''''. {{doi|10.1021/ac60053a04}}</ref>
<ref name=>O.V.Netskina, O.V.Komova, S.A.Mukha, V.I.Simagina: "Aqueous-alkaline NaBH4 solutions: The influence of hydride decomposition on catalytic properties of Co3O4". ''''. {{doi|10.1016/j.catcom.2016.07.004}}</ref>
<ref name=>Zhou, Yong-Quan; Fang, Chun-Hui; Fang, Yan (2010): "Structure of Supersaturated Aqueous SodiumPentaborate Solution". Acta Physico-Chimica Sinica, volume 26, Number 9, 15 September , pp. 2323-2330(8) [DOI]
<ref name=>G. Pasupathi and P. Philominathan: "Growth and Characterization of Sodium Penta Borate Single Crystals: an Inorganic NLO Material". ''International Journal of Electronic Engineering Research ISSN 0975 - 6450 volume 2 Number 1 (2010) pp. 79–85 '' [DOI]
<ref name=>A. Sundari, S. Manikandan: "Third order nonlinear optical properties and optical limiting behaviour of sodium penta borate". ''''. {{doi|10.1007/s10854-017-7947-6}}</ref>
<ref name=>S.Stella Mary, S.Shahil Kirupavathy, P.Mythili, R.Gopalakrishnan: "Growth and characterization of sodium pentaborate [Na(H4B5O10)] single crystals". ''''. {{doi|10.1016/j.saa.2008.04.021}}</ref>
<ref name=>Nelson P. Nies, Richard W. Hulbert: "Solubility Isotherms in the System Sodium Oxide-Boric Oxide-Water: Revised Solubility-Temperature Curves of Boric Acid, Borax, Sodium Pentaborate, and Sodium Metaborate". ''''. {{doi|10.1021/je60034a005}}</ref>
<ref name=>Robert K. Momii, Norman H. Nachtrieb: "Nuclear Magnetic Resonance Study of Borate-Polyborate Equilibria in Aqueous Solution". ''''. {{doi|10.1021/ic50052a026}}</ref>
<ref name=>S. Menchetti and C. Sabelli: "The crystal structure of synthetic sodium pentaborate monohydrate". ''''. {{doi|10.1107/S0567740877011959}}</ref>

Last edited on 2022-07-27 07:53:15 by stolfi