@Article{B608029D, author ="Chandran, Sreekanth K. and Nangia, Ashwini", title ="Modulated crystal structure (Z′ = 2) of α-d-glucofuranose-1{,}2∶3{,}5-bis(p-tolyl)boronate", journal ="CrystEngComm", year ="2006", volume ="8", issue ="8", pages ="581-585", publisher ="The Royal Society of Chemistry", doi ="10.1039/B608029D", url ="http://dx.doi.org/10.1039/B608029D", abstract ="The 1∶2 complex of α-d-glucose and p-tolylboronic acid (1) crystallizes in α-glucofuranose form at room temperature in P212121 space group with one molecule in the asymmetric unit (Z′ = 1). Data collection at 100 K afforded a modulated structure in P21 space group and Z′ = 2. Interestingly{,} C–H⋯O interactions are shown to relate with multiple molecular conformations and Z′ > 1. There is no change in the crystal structure of α-d-glucofuranose-1{,}2∶3{,}5-bis(phenyl)boronate (2) between 100–298 K."}