
<ref name=deme1955>T. Demediuk, W. F. Cole, H. V. Hueber (1955): "Studies on magnesium and calcium oxychlorides". ''Australian Journal of Chemistry'', volume 8, issue 2, pages 215-233. {{doi|10.1071/CH9550215}}</ref>

  "The reactions which take place in the system MgO-MgCl2-H2O at
  concentrations of MgCl2 solutions up to 45 per cent. and
  temperatures from 0 to 110 °C have been studied in detail. Four
  oxychlorides have been found, namely, 9Mg(OH)2.MgCl2.5H2O,
  5Mg(OH)2.MgCl2.8H2O, 3Mg(OH)2.MgCl2.8H2O, and 2Mg(OH)2.MgCl2.4H2O ;
  and an equilibrium diagram has been produced which gives the
  conditions at which each is stable. It is probable that in the
  formation of the oxychlorides a complex ion forms first and this
  reacts with Mg(OH)2, formed by rapid hydration of MgO, to produce
  amorphous oxychloride gels which slowly crystallize. The reactions
  in the systems MgO-CaCl2-H2O, CaO-MgCl2-H2O, Ca(OH)2-MgCl2-H2O,
  CaO-CaCl2-H2O, Ca(OH)2-CaCl2-H2O, and between calcined dolomite and
  MgCl2, or CaCl2. solutions have been studied briefly. Oxychlorides
  form in these reactions also. It is therefore suggested that the
  explanation for the success of the method of Demediuk (1952) for the
  removal of " unsoundness " of dolomitic limes, and other limes high
  in magnesium oxide, by the action of salt solutions lies in the
  conversion of free magnesium oxide to magnesium oxychlorides. The
  optical properties and stabilities of the magnesium oxychlorides are
  briefly discussed."

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