# Last edited on 2018-08-13 15:40:45 by stolfilocal # https://pubs.acs.org/doi/pdf/10.1021/acs.jced.5b00224 # Determination of the Solubility of Ammonium Dihydrogen Phosphate in Water-Ethanol System at Different Temperatures from 283.2 to 343.2 K # Dejun Xu, Xing Xiong, Lin Yang, Zhiye Zhang, and Xinlong Wang # Journal of Chemincal Engineering Data, 2016, volume 61, issue 1, pages 78–82 # DOI: 10.1021/acs.jced.5b00224 # Molar mass (NH4)H2PO4 = 115.0 g # Molar mass H2O = 18.01528 g # Molar mass ethanol = 46.07 g # # Various data points from YouTube etc: # 20 C 36.5 g/dL # 80 C 118.0 g/dL 18.01528 # Temperature (K,C), experimental mole fraction, literature mole fraction, mass fraction, solubility g/dL ------+---------+------- # pure water 283.2 | 10.0 | 0.0425 | 0.0411 | 0.2208 | 28.3 293.2 | 20.0 | 0.0528 | 0.0533 | 0.2625 | 35.6 303.2 | 30.0 | 0.0644 | 0.0663 | 0.3053 | 43.9 313.2 | 40.0 | 0.0808 | 0.0806 | 0.3595 | 56.1 323.2 | 50.0 | 0.0937 | 0.0976 | 0.3976 | 66.0 333.2 | 60.0 | 0.1130 | 0.1153 | 0.4485 | 81.3 # Temperature (K,C), experimental mole fraction (%), error from fitted formula (%), mass fraction, solubility g/dL ------+---------+------- # pure water 283.2 | 10.0 | 0.0425 | -2.81 | 0.2209 | 28.36 293.2 | 20.0 | 0.0528 | -0.85 | 0.2626 | 35.62 303.2 | 30.0 | 0.0644 | -0.38 | 0.3054 | 43.97 313.2 | 40.0 | 0.0808 | +3.25 | 0.3595 | 56.13 323.2 | 50.0 | 0.0938 | -0.37 | 0.3979 | 66.08 333.2 | 60.0 | 0.1131 | +0.13 | 0.4487 | 81.39 343.2 | 70.0 | 0.1343 | -0.44 | 0.4977 | 99.09 ------+---------+------- # mass fraction of ethanol = 10.00% 283.2 | 10.0 | 0.0212 | -6.40 | 0.1216 | 13.85 293.2 | 20.0 | 0.0308 | +1.42 | 0.1687 | 20.29 303.2 | 30.0 | 0.0405 | +0.35 | 0.2122 | 26.94 313.2 | 40.0 | 0.0540 | +1.80 | 0.2673 | 36.47 323.2 | 50.0 | 0.0692 | +0.01 | 0.3217 | 47.44 333.2 | 60.0 | 0.0895 | +0.20 | 0.3856 | 62.75 343.2 | 70.0 | 0.1143 | -0.09 | 0.4517 | 82.39 ------+---------+------- # mass fraction of ethanol = 20.00% 283.2 | 10.0 | 0.0107 | -11.29 | 0.0647 | 6.92 293.2 | 20.0 | 0.0163 | -2.15 | 0.0958 | 10.60 303.2 | 30.0 | 0.0238 | +2.49 | 0.1348 | 15.58 313.2 | 40.0 | 0.0327 | +1.48 | 0.1774 | 21.57 323.2 | 50.0 | 0.0443 | -0.33 | 0.2282 | 29.57 333.2 | 60.0 | 0.0616 | +1.01 | 0.2954 | 41.93 343.2 | 70.0 | 0.0829 | -0.58 | 0.3659 | 57.70 ------+---------+------- # mass fraction of ethanol = 30.00% 283.2 | 10.0 | 0.0056 | -3.48 | 0.0346 | 3.58 293.2 | 20.0 | 0.0095 | +9.35 | 0.0577 | 6.12 303.2 | 30.0 | 0.0137 | +6.67 | 0.0812 | 8.84 313.2 | 40.0 | 0.0188 | +0.53 | 0.1091 | 12.24 323.2 | 50.0 | 0.0264 | -3.38 | 0.1474 | 17.29 333.2 | 60.0 | 0.0383 | -2.82 | 0.2028 | 25.43 343.2 | 70.0 | 0.0573 | +1.43 | 0.2797 | 38.84 ------+---------+------- # mass fraction of ethanol = 40.00% 0.0 | -273.2 | 0.0000 | +0.00 | 0.0000 | 0.00 283.2 | 10.0 | 0.0026 | -5.35 | 0.0162 | 1.65 293.2 | 20.0 | 0.0048 | +10.99 | 0.0297 | 3.06 303.2 | 30.0 | 0.0074 | +10.86 | 0.0453 | 4.74 313.2 | 40.0 | 0.0103 | +3.04 | 0.0626 | 6.68 323.2 | 50.0 | 0.0147 | -3.15 | 0.0869 | 9.51 333.2 | 60.0 | 0.0213 | -6.00 | 0.1219 | 13.89 343.2 | 70.0 | 0.0340 | +2.24 | 0.1837 | 22.50 ------+---------+------- # mass fraction of ethanol = 50.00% 283.2 | 10.0 | 0.0014 | -21.04 | 0.0086 | 0.87 293.2 | 20.0 | 0.0024 | -2.26 | 0.0149 | 1.52 303.2 | 30.0 | 0.0039 | +8.97 | 0.0243 | 2.49 313.2 | 40.0 | 0.0053 | +2.71 | 0.0327 | 3.38 323.2 | 50.0 | 0.0075 | +1.32 | 0.0457 | 4.79 333.2 | 60.0 | 0.0099 | -5.71 | 0.0599 | 6.38 343.2 | 70.0 | 0.0150 | +1.74 | 0.0886 | 9.72 ------+---------+------- # mass fraction of ethanol = 60.00% 283.2 | 10.0 | 0.0008 | -6.77 | 0.0054 | 0.54 293.2 | 20.0 | 0.0012 | -4.59 | 0.0079 | 0.79 303.2 | 30.0 | 0.0018 | +1.82 | 0.0117 | 1.18 313.2 | 40.0 | 0.0026 | +4.56 | 0.0163 | 1.66 323.2 | 50.0 | 0.0033 | -0.63 | 0.0207 | 2.11 333.2 | 60.0 | 0.0043 | -1.17 | 0.0269 | 2.77 343.2 | 70.0 | 0.0057 | +0.34 | 0.0351 | 3.64 ------+---------+------- # mass fraction of ethanol = 70.00% 283.2 | 10.0 | 0.0006 | -2.07 | 0.0035 | 0.36 293.2 | 20.0 | 0.0007 | +0.58 | 0.0046 | 0.46 303.2 | 30.0 | 0.0009 | +2.02 | 0.0058 | 0.58 313.2 | 40.0 | 0.0011 | -0.61 | 0.0069 | 0.69 323.2 | 50.0 | 0.0013 | -0.17 | 0.0084 | 0.84 333.2 | 60.0 | 0.0016 | -0.59 | 0.0100 | 1.01 343.2 | 70.0 | 0.0019 | +0.33 | 0.0119 | 1.20 ------+---------+------- # mass fraction of ethanol = 80.00% 283.2 | 10.0 | 0.0002 | -2.09 | 0.0013 | 0.13 293.2 | 20.0 | 0.0002 | -2.09 | 0.0016 | 0.16 303.2 | 30.0 | 0.0003 | +4.62 | 0.0020 | 0.20 313.2 | 40.0 | 0.0004 | +0.72 | 0.0022 | 0.22 323.2 | 50.0 | 0.0004 | -0.31 | 0.0026 | 0.26 333.2 | 60.0 | 0.0005 | -3.35 | 0.0029 | 0.29 343.2 | 70.0 | 0.0005 | +1.59 | 0.0035 | 0.35 ------+---------+------- # mass fraction of ethanol = 90.00% 283.2 | 10.0 | 0.0001 | -0.05 | 0.0004 | 0.04 293.2 | 20.0 | 0.0001 | -1.41 | 0.0004 | 0.04 303.2 | 30.0 | 0.0001 | +1.12 | 0.0005 | 0.05 313.2 | 40.0 | 0.0001 | -0.49 | 0.0005 | 0.05 323.2 | 50.0 | 0.0001 | +0.35 | 0.0006 | 0.06 333.2 | 60.0 | 0.0001 | -1.17 | 0.0007 | 0.07 343.2 | 70.0 | 0.0001 | +0.50 | 0.0008 | 0.08 ------+---------+-------